This card is from the Burning Shadows Set
This card is straight from pack.
Pokemon Single Card - Burning Shadows 001/147 Caterpie Common Pack Fresh
Pokemon Single Card - Burning Shadows 002/147 Metapod Uncommon Pack Fresh
Pokemon Single Card - Burning Shadows 003/147 Butterfree Rare Pack Fresh
Pokemon Single Card - Burning Shadows 005/147 Gloom Uncommon Pack Fresh
Pokemon Single Card - Burning Shadows 007/147 Tangela Common Pack Fresh